Synthesis and physico-chemical properties of the first water soluble Cu(II)@hemicryptophane complex - INAC-SCIB
Article Dans Une Revue Organic & Biomolecular Chemistry Année : 2015

Synthesis and physico-chemical properties of the first water soluble Cu(II)@hemicryptophane complex

Résumé

A hemicryptophane ligand soluble in water at neutral pH was obtained thanks to the derivatization of the cyclotribenzylene unit with three carboxylate groups. The corresponding Cu(II) complex was then synthesized and its spectroscopic and electrochemical properties in water were investigated, showing that water solubilisation retains the geometry of the complex around the metal center but strongly affects its redox properties, compared to previously reported Cu(II)@hemicryptophane complexes soluble in organic solvents.
Fichier principal
Vignette du fichier
c4ob02085e.pdf; (487.25 Ko) Télécharger le fichier
Origine Publication financée par une institution

Dates et versions

hal-01473697 , version 1 (14-11-2024)

Identifiants

Citer

Aline Schmitt, Solène Collin, Christophe Bucher, Vincent Maurel, Jean-Pierre Dutasta, et al.. Synthesis and physico-chemical properties of the first water soluble Cu(II)@hemicryptophane complex. Organic & Biomolecular Chemistry, 2015, 13 (7), pp.2157-2161. ⟨10.1039/c4ob02085e⟩. ⟨hal-01473697⟩
132 Consultations
0 Téléchargements

Altmetric

Partager

More